Abdel Mouin told CNN by phone from Tripoli that the family was notified by his lawyer in the United States that al Libi, whose real name was Nazih al-Ruqaii, died in a hospital Friday evening.
The 50-year-old native of Libya was accused of playing a role in the 1998 U.S. Embassy bombings in Kenya and Tanzania. The two bombings killed 224 people, including 12 Americans, and injured thousands more.
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His wife said at the time of his capture that he was no longer a member of al Qaeda, had been living a normal life and was seeking a job with the Libyan oil ministry.
CNN’s Evan Perez and Laura Smith-Spark contributed to this report.